承担 的主 要项 目及 成果 | 主持科研项目: (1) 国家自然科学基金青年项目(21908139),Ce配合物设计合成及其绿色高效催化芳烃硝化反应机理研究,2020-01至2022-12,主持; (2) 陕西省自然科学基础研究计划项目(2019JQ-782),硝酸铈铵体系芳烃绿色硝化反应机理研究,2019-01至2020-12,主持; (3) 陕西省教育厅专项科研计划项目(19JK0149),Ce配合物催化芳烃硝化反应机理及选择性研究,2019-01至2020-12,主持; (4) 氟氮化工资源高效开发与利用国家重点实验室开放课题-重点项目(204-2021-1404,10万),高温室效应值三氟甲烷转化利用研究,2021-10至2023-10,主持; (5) 企业横向项目(20万),A**关键前体生长机理及热动力学研究,2018-09至2019-09,主持; (6) 陕西科技大学博士科研启动经费(2018BJ-40),硝酸铈铵体系芳烃硝化反应机理与动力学研究,主持. 获奖情况: (1) 芳烃直接氧化制备酚类的催化剂构筑及性能研究, 陕西省教育厅, 2022年度陕西高等学校科学技术研究优秀成果奖, 二等奖. (2) 高效负载型钯系催化剂的设计制备及应用, 陕西省人民政府, 2020年度陕西省科学技术进步奖, 一等奖. (3) 高压/超临界原位红外光谱关键技术及应用, 陕西省教育厅, 2019年度陕西高等学校科学技术奖, 一等奖. 已发表SCI论文60余篇,申请/授权中国发明专利20余件,部分代表性成果如下: 代表性论文: (1) Kuan Wang,* Run-Jing You, Hui Ma, Tong Sun, Zhen-Hong He, Jian-Gang Chen, Huan Wang, Weitao Wang, Yang Yang, Zhao-Tie Liu,* Construction of a Z-scheme heterojunction photocatalyst with oxygen vacancies using cobalt–alumina-layered double hydroxide dispersed between bismuth oxybromide layers for efficient photocatalytic reduction of carbon dioxide, J. Colloid Interface Sci., 2024, 654, 988-1000. (2) Kuan Wang,* Dan Wang, Xiao-Yong Zhang, Junlei Wang, Sheng-Li Lv, Zhen-Hong He, Huan Wang, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Modular calcination strategy to construct defect-rich nitrogen-doped Nb2O5 for boosting photocatalytic oxidation of cyclohexane to cyclohexanone in solvent-free conditions, Appl. Surf. Sci., 2023, 617, 156600. (3) Junlei Wang, Kuan Wang,* Zhen-Hong He, Tong Sun, Run-Jing You, Jian-Gang Chen, Weitao Wang, Yang Yang, Zhao-Tie Liu,* Construction of Bi2WO6 with double active sites of tunable metallic Bi and oxygen vacancies for photocatalytic oxidation of cyclohexane to cyclohexanone, Dalton Tran., 2023, 52, 476-486. (4) Kuan Wang, Heng Yang, Zhe Cao, Hui Ma, Zhen-Hong He, Jian-Gang Chen, Huan Wang, Weitao Wang, Jian Lu, Zhao-Tie Liu, Eco-friendly nitration of acetanilide over MCM-41-supported CeCuCoOx catalyst: A solid acidic catalysis strategy, Mol. Catal., 2023, 542, 113145. (5) Junlei Wang, Kuan Wang*, Zhen-Hong He, Rong-Rong Zhang, Pengfei Guo, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Constructing of ultrathin Bi2WO6/BiOCl nanosheets with oxygen vacancies for photocatalytic oxidation of cyclohexane with air in solvent-free, Appl. Surf. Sci., 2022, 584, 152606. (6) Kuan Wang*, Song-Song Li, Junlei Wang, Zhen-Hong He, Dan Wang, Rong-Rong Zhang, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Photothermal oxidation of cyclohexane over CoLaOx/WO3 Z-scheme composites with p-n heterojunction in solvent-free conditions, Catal. Today, 2022, 409, 42-52. (7) Kuan Wang*, Zhe Cao, Junlei Wang, Zhen-Hong He, Dan Wang, Rong-Rong Zhang, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Efficient and selective hydrogenation of quinolines over FeNiCu/MCM-41 catalyst at low temperature: Synergism of Fe-Ni and Ni-Cu alloys, Mol. Catal., 2022, 520, 112166. (8) Junlei Wang, Kuan Wang*, Zhen-Hong He, Song-Song Li, Rong-Rong Zhang, Pengfei Guo, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Solvent‑induced synthesis of hierarchical TiO2 nanoflowers with tunable morphology by monolayer self‑assembly for probing the photocatalytic performance, J. Nanostructure Chem., 2022, 12, 1075-1087. (9) Kuan Wang*, Bing Xue, Jun-Lei Wang, Zhen-Hong He, Song-Song Li, Dan Wang, Wei-Tao Wang, Yang Yang, Zhao-Tie Liu*, Construction of indium oxide/N-doped titanium dioxide hybrid photocatalysts for efficient and selective oxidation of cyclohexane to cyclohexanone, J. Phys. Chem. C, 2021, 125, 19791-19801. (10) Kuan Wang*, Bing Xue, Jun-Lei Wang, Zhen-Hong He, Xiao-Yong Zhang, Song-Song Li, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Efficient and selective oxidation of cyclohexane to cyclohexanone over flake hexagonal boron nitride/titanium dioxide hybrid photocatalysts, Mol. Catal., 2021, 505, 111530. (11) Kuan Wang*, Jie Lan, Zhen-Hong He, Zhe Cao, Weitao Wang, Yang Yang, Zhao-Tie Liu*, Experimental and density functional theory studies on hydroxymethylation of phenylboronic acids with paraformaldehyde over a Rh-PPh3 catalyst, Appl. Organomet. Chem., 2021, 35, e6104. (12) Kuan Wang*, Bing Xue, Jian-Gang Chen*, Zhen-Hong He, Yueping Ji, Bozhou Wang, Jian Lu, Zhong-Wen Liu, Zhao-Tie Liu*, A combined experimental and theoretical study of the thermal decomposition mechanism and kinetics of ammonium dinitramide (ADN),New J. Chem., 2020, 44, 6833-6844. (13) Qiang He, Kuan Wang, Jian-Gang Chen*, Zhen-Hong He, Zhao-Tie Liu*, Zhong-Wen Liu, Jian Lu*, Interaction between ammonium perfluorooctanoate and CO2 and its removal from fluoropolymer in supercritical carbon dioxide, Sep. Purif. Technol., 2020, 232, 115955. (14) Xiufang Yang, Xulu Jiang, Weitao Wang*, Qi Yang, Yangmin Ma, Kuan Wang*, Catalyst- and solvent-free ipso-hydroxylation of arylboronic acids to phenols, RSC Adv., 2019, 9, 34529–34534. (15) Kuan Wang, Jian-Gang Chen*, Zhan-Bin Nie, Zhao-Tie Liu*, Yueping Ji, Bozhou Wang, Fengyi Liu, Zhong-Wen Liu, Wenliang Wang, Jian Lu*, Impacts of the acidic group on the hydrolysis of 2-dinitromethylene-5,5-dinitropyrimidine-4,6-dione, RSC Adv., 2018, 8, 13301-13309. (16) Kun Dai#, Kuan Wang#, Yang Li, Jian-Gang Chen*, Zhong-Wen Liu, Jian Lu, Zhao-Tie Liu*, Construction of β-trifluoromethyl enol ether via base-promoted C-O coupling and rearrangement of hydrogen atom, J. Org. Chem., 2017, 82, 4721-4728. (17) Kuan Wang, Jian-Gang Chen*, Bozhou Wang, Yueping Ji, Fengyi Liu, Zhao-Tie Liu*, Wenliang Wang, Zhong-Wen Liu, Zhengping Hao, Jian Lu*, Insight into the acidic group-induced nitration mechanism of 2-methyl-4,6-dihydroxy-pyrimidine (MDP) with nitronium, RSC Adv., 2016, 6, 80145-80157. (18) Kuan Wang, Jian-Gang Chen*, Bozhou Wang, Fengyi Liu, Zhao-Tie Liu*, Zhong-Wen Liu, Wenliang Wang, Jinqiang Jiang, Zhengping Hao, Jian Lu*, Density functional theory study on the reaction of triazol-3-one with nitronium: Direct nitration versus acidic group-induced nitration, RSC Adv., 2015, 5, 25183-25191. (19) 王宽, 陈建刚*, 王伯周, 吕剑, 王文亮, 刘峰毅, 周诚, 廉鹏, 刘忠文, 刘昭铁*, FOX-12制备过程的反应机理及动力学, 高等学校化学学报, 2015, 36, 531-538. 发明专利: (1) 王宽, 吕生立, 党同乐, 刘昭铁, 何珍红, 王伟涛, 王欢, 一种三元型 HxV2O5/LaVO4/WO3催化剂及其制备方法和应用, 中国, 申请号: CN2023112444341. (2) 王宽, 李鑫鹏, 马辉, 刘昭铁, 何珍红, 王伟涛, 王欢, 一种含三氟甲基苯并呋喃衍生物及其制备方法, 中国, 申请号: CN2023114229710. (3) 王宽, 李鑫鹏, 马辉, 刘昭铁, 何珍红, 王伟涛, 王欢, 一种基于氟仿制备的含三氟甲基吡啶衍生物及方法, 中国, 申请号: CN2023114267110. (4) 王宽, 李鑫鹏, 马辉, 刘昭铁, 何珍红, 王伟涛, 王欢, 中国, 基于硫氰酸亚铜催化制备的含三氟甲基喹啉衍生物及方法, 申请号: CN2023114226958. (5) 王宽, 吕生立, 杨恒, 刘昭铁, 何珍红, 王伟涛, 杨阳, 王欢, 一种具有光热催化活性的WFemLanOx催化剂及其制备方法和应用, 中国, 申请号: CN202211575245.8. (6) 王宽, 王忠宇, 何珍红, 刘昭铁, 王伟涛, 杨阳, 一种In2.24(NCN)3粉体的制备方法,中国,申请号: CN201910495818.8, 授权日: 2022.06.14. (7) 何珍红, 王忠宇, 王宽, 刘昭铁, 王伟涛, 杨阳, 一种In2.24(NCN)3催化硝基苯加氢还原制备苯胺的方法, 中国, 申请号: CN201910496113.8, 授权日: 2022.02.25. (8) 陈建刚, 王宽, 刘昭铁, 王伯周, 刘忠文, 周成, 廉鹏, 含能材料制备过程硝化反应热效应测量方法, 中国, ZL201410663685.8. (9) 陈建刚, 王宽, 刘昭铁, 沈淑坤, 周改改, 刘忠文, 江金强, 宋丽萍, 在线监测超临界体系的高压紫外可见近红外光谱装置, 中国, ZL201310752756.7. |