一、作为项目负责人,承担项目: 7、国家自然科学基金面上项目:22075169,双组分离子型HOFs材料的制备及质子交换膜应用性能研究,63万元;(2021.01~2024.12) 6、国家自然科学基金青年项目:21701106,基于配体置换的金属有机框架材料光聚合反应研究,24万元;(2018.01~2020.12) 5、中国博士后科学基金面上项目:2019M653852XB,基于配体交换的MOFs后合成机理与性质变化的研究,8万元;(2019.07~2021.07) 4、陕西基础科学研究院科学研究计划项目:22JHQ026,离子型HOF超分子材料的制备及PEMFC应用性能研究,5万元;(2023.01~2024.12) 3、陕西省科技厅基础研究计划项目:2018JQ2005,多孔发光MOF材料负载染料分子的主-客体FRET过程研究,3万元;(2018.01~2019.12) 2、陕西省教育厅专项项目:17JK0090,金属有机框架材料捕获和协同催化转化CO2的研究,2万元;(2017.01~2018.12) 1、陕西科技大学青年拔尖人才科研启动基金:2016QNBJ-11,基于新型芳香羧酸配体的多孔配位聚合物的制备、结构转变及其吸附分离性质的研究,60万元。(2016.07~2020.12) 二、以第一作者或通讯作者,发表论文: 23. Xiao-Jie Cao, Li-Hui Cao*, Xiang-Tian Bai, Xiao-Ying Hou, and Hai-Yang Li, An Ultra-Robust and 3D Proton Transport Pathways iHOF with Single-Crystal Superprotonic Conductivity Around 0.4 S cm−1, Adv. Funct. Mater., 2024, 34, 2409359. (IF2023=18.5) 22. Xiang-Tian Bai, Li-Hui Cao*, Xu-Yong Chen, Shu-Hui Li, Jia-Hao Zhang, Dimethylamine-tuned guanidinium arylphosphonate iHOFs and superprotonic conduction Nafion hybrid membranes for DMFCs, Chem. Eng. J., 2024, 487, 150747. (IF2023=13.3) 21. Xiang-Tian Bai, Li-Hui Cao*, Xu-Yong Chen, Jia-Yu Wang, Zi-Ye Zhou, Multivariate Synergy for Heighten Ionic HOF Robustness and Proton Conductivity, Sci. China Chem., 2024, DOI: 10.1007/s11426-024-2352-9. (IF2023=10.4) 20. Xiang-Tian Bai, Li-Hui Cao*, Fang Zhao, and Shu-Hui Li, Arylsulfonate Ionic Hydrogen-Bonded Organic Frameworks Enable Highly Stable and Superprotonic Conductivity for Enhancing Direct Methanol Fuel Cells, ACS Materials Lett., 2024, 6, 3351−3357. (IF2023=9.6) 19. Bin Zhou, Li-Hui Cao*, Bing-Sha Li, Xu-Yong Chen, Xiang-Tian Bai, Ionic Hydrogen-Bonded Organic Frameworks with a Two-Photon Synergistic Color Change and Their Information Encryption Applications, ACS Appl. Mater. Interfaces, 2024, 16, DOI:10.1021/acsami.4c15701. (IF2023=8.3) 18. Xiang-Tian Bai, Li-Hui Cao*, Yan Yang and Xu-Yong Chen, Multi-interpenetration driven ultra-robust ionic HOF with high proton conductivity for DMFCs, Chem. Commun., 2024, 60, 11576–11579. (IF2023=4.3) 17. Ming-Feng Huang, Li-Hui Cao*, and Bin Zhou, A solvent-controlled photoresponsive ionic hydrogen-bonded organic framework for encryption applications, Chem. Commun., 2024, 60, 3437–3440. (IF2023=4.3) 16. Xu-Yong Chen, Li-Hui Cao*, Xiang-Tian Bai, and Xiao-Jie Cao, Charge-Assisted Ionic Hydrogen-Bonded Organic Frameworks: Designable and Stabilized Multifunctional Materials, Chem. Eur. J., 2024, 30, e202303580. (Invited Review, IF2023=3.9) 15. Dan Yang, Xu-Yong Chen*, Li-Hui Cao*, High proton conductivity of sulfonate-amine ionic HOFs and enhancement of SPEEK composite membranes, Chem Asian J., 2024, 19, DOI:10.1002/asia.202400870. (IF2023=3.5) 14. Xiang-Tian Bai, Li-Hui Cao*, Can Ji, Fang Zhao, Xu-Yong Chen, Xiao-Jie Cao, and Ming-Feng Huang, Ultra-High Proton Conductivity iHOF Based on Guanidinium Arylphosphonate for Proton Exchange Membrane Fuel Cells, Chem. Mater., 2023, 35, 3172−3180. (IF2023=7.2) 13. Xu-Yong Chen, Li-Hui Cao*, Xiang-Tian Bai, Xiao-Jie Cao, Dan Yang, and Yi-Da Gao, Superprotonic Conductivity of Guanidinium Organosulfonate Hydrogen-Bonded Organic Frameworks with Nanotube-Shaped Proton Transport Channels, Precis. Chem., 2023, 1, 608−615. 12. Fang Zhao, Li-Hui Cao*, and Can Ji, Proton conduction of an ionic HOF with multiple water molecules and application as a membrane filler in direct methanol fuel cells, J. Mater. Chem. C, 2023, 11, 15288-15293. (IF2023=5.7) 11. Xu-Yong Chen, Li-Hui Cao*, Ming-Feng Huang, Yan Yang, Yi-Da Gao, Xiang-Tian Bai, and Dan Yang, Water-Induced Single-Crystal to Single-Crystal Transformation of Ionic Hydrogen-Bonded Organic Frameworks with Enhanced Proton Conductivity, Chem. Eur. J., 2023, 29, e202300028. (IF2023=3.9) 10. Xiang-Tian Bai, Li-Hui Cao*, Xu-Yong Chen, Xiao-Jie Cao, Wan-Cai Meng, and Kai-Yang Yan, A Sodium-Based Phosphonates Metal−Organic Framework with Superprotonic Conductivity, Cryst. Growth Des., 2023, 23, 8488−8493. (IF2023=3.2) 9. Fang Zhao, Li-Hui Cao* Xiang-Tian Bai, Xu-Yong Chen, and Zheng Yin, Application of Ionic Hydrogen-Bonded Organic Framework Materials in Hybrid Proton Exchange Membranes, Cryst. Growth Des., 2023, 23, 1798−1804. (IF2023=3.2) 8. Yan Yang, Xu-Yong Chen, Xin-Mei Li, Fang Zhao, Xiang-Tian Bai and Li-Hui Cao*, Enhanced proton conduction of crystalline organic salt hybrid membranes and the performance of fuel cells, Mater. Chem. Front., 2022, 6, 3402–3408. (IF2022=7.0) 7. Yu-Wen Tang, Xu-Yong Chen, Fang Zhao, Xiang-Tian Bai, Zheng Yin, and Li-Hui Cao*, Enhanced Proton Conductivity of an Ionic Hydrogen-Bonded Organic Framework-Embedded Nafion Matrix, Energy Fuels, 2022, 36, 12772−12779. (IF2022=5.3) 6. Li-Hui Cao*, Yan Yang, Xiao-Han Tang, Xu Wang, and Zheng Yin, Substituent Controlled Framework Transformation Based on Solvent-Assisted Linker Exchange, Cryst. Growth Des. 2022, 22, 37-42. (IF2022=3.8) 5. Xiao-Qian Xu, Li-Hui Cao*, Yan Yang, Fang Zhao, Xiang-Tian Bai, and Shuang-Quan Zang, Hybrid Nafion Membranes of Ionic Hydrogen-Bonded Organic Framework Materials for Proton Conduction and PEMFC Applications, ACS Appl. Mater. Interfaces 2021, 13, 56566−56574. (IF2021=10.383) 4. Li-Hui Cao*, Xiao-Qian Xu, Xiao-Han Tang, Yan Yang, Junyi Liu, Zheng Yin, Shuang-Quan Zang, and Yang-Min Ma, Controllable Strategy for Metal−Organic Framework Light-Driven [2 + 2] Cycloaddition Reactions via Solvent-Assisted Linker Exchange, Inorg. Chem. 2021, 60, 2117−2121. (Supplementary Cover, IF2021=5.436) 3. Xiao-Qian Xu, Li-Hui Cao*, Yan Yang, Xiang-Tian Bai, Fang Zhao, Zhen-Hong He, Zheng Yin, and Yang-Min Ma, Cationic Nonporous Macrocyclic Organic Compounds for Multimedia Iodine Capture, Chem Asian J. 2021, 16, 142−146. (IF2021=4.839) 2. Li-Hui Cao*, Xin Liu, Xiao-Han Tang, Junyi Liu, Xiao-Qian Xu, Shuang-Quan Zang and Yang-Min Ma, A fivefold linker length reduction in an interpenetrated metal–organic framework via sequential solvent-assisted linker exchange, Chem. Commun. 2019, 55, 12671−12674. (IF2019=5.996) 1. Li-Hui Cao, Hai-Yang Li, Hong Xu, Yong-Li Wei* and Shuang-Quan Zang*, Diverse dissolution–recrystallization structural transformations and sequential Förster resonance energy transfer behavior of a luminescent porous Cd-MOF, Dalton Trans. 2017, 46, 11656–11663. (IF2017=4.099) Before SUST: 7. Li-Hui Cao, Yong-Sheng Wei, Hong Xu, Shuang-Quan Zang*, and Thomas C. W. Mak, Unveiling the Mechanism of Water-Triggered Diplex Transformation and Correlating the Changes in Structures and Separation Properties, Adv. Funct. Mater. 2015, 25, 6448−6457. (Back Cover) 6. Li-Hui Cao, Fang Shi, Wen-Min Zhang, Shuang-Quan Zang*, and Thomas C. W. Mak, Selective Sensing of Fe3+ and Al3+ Ions and Detection of 2,4,6-Trinitrophenol by a Water-Stable Terbium-Based Metal–Organic Framework, Chem. Eur. J. 2015, 21, 15705−15712. (高被引论文) 5. Li-Hui Cao, Yong-Li Wei, Yang Yang, Hong Xu, Shuang-Quan Zang*, Hong-Wei Hou, and Thomas C. W. Mak, Crystal Structures and Properties of Cd(II) Coordination Polymers Supported by a New Chiral Aromatic Polycarboxylate Ligand, Cryst. Growth Des. 2014, 14, 1827−1838. 4. Li-Hui Cao, Yong-Li Wei, Can Ji, Ming-Li Ma, Shuang-Quan Zang*, and Thomas C. W. Mak, A Multifunctional 3D Chiral Porous Ferroelectric Metal–Organic Framework for Sensing Small Organic Molecules and Dye Uptake, Chem. Asian J. 2014, 9, 3094−3098. 3. Li-Hui Cao, Qing-Qing Xu, Shuang-Quan Zang*, Hong-Wei Hou, and Thomas C. W. Mak, First Three-Dimensional Self-Penetrating Coordination Polymer Containing Rare (10,3)‑d Subnets: Synthesis, Structure, and Properties, Cryst. Growth Des. 2013, 13, 1812−1814. 2. Li-Hui Cao, Hai-Yang Li, Shuang-Quan Zang*, Hong-Wei Hou and Thomas C. W. Mak, (4,4)-Connected Self-penetrating Pillared-Layered Metal−Organic Framework Based on a Nanosized Flexible Aromatic Carboxylic Acid Ligand, Cryst. Growth Des. 2012, 12, 4299−4301. 1. Shuang-Quan Zang*, Li-Hui Cao, Ran Liang, Hong-Wei Hou, and Thomas C. W. Mak, Divalent Zinc, Cobalt, and Cadmium Coordination Polymers of a New Flexible Trifunctional Ligand: Syntheses, Crystal Structures, and Properties, Cryst. Growth Des. 2012, 12, 1830−1837. 三、授权专利: 10、曹丽慧,赵芳,杨妍,白向田,黄明峰,曹萧杰,“一种基于五重互穿氢键有机框架材料及其制备方法和应用”,专利号:ZL202211214145.2; 9、曹丽慧,赵芳,白向田,杨妍,陈绪永,“苯磺酸基离子型氢键有机框架材料及其制备方法和应用”,专利号:ZL202210794791.4; 8、曹丽慧,杨妍,赵芳,白向田,“一种晶态有机盐及其制备方法和应用”,专利号:ZL202111408624.3; 7、曹丽慧,白向田,赵芳,陈绪永,“一种三维金属钠配位聚合物及其制备方法和应用”,专利号:ZL202210841664.5; 6、曹丽慧,白向田,赵芳,陈绪永,曹萧杰,黄明峰,“一种胍基磷酸盐氢键有机框架材料及其制备方法和应用”,专利号:ZL202210862003.0; 5、曹丽慧,徐小倩,杨妍,白向田,赵芳,“一种离子型氢键有机骨架材料及其制备方法和应用”,专利号:ZL202110431340.X; 4、曹丽慧,唐于雯,周家成,王旭,“一种三维金属镉配位聚合物及其制备方法”,专利号:ZL202110513413.X; 3、曹丽慧,杨妍,徐小倩,白向田,赵芳,“一种离子型氢键有机框架材料及其制备方法和应用”,专利号:ZL202011453319.1; 2、曹丽慧,徐小倩,杨妍,白向田,赵芳,马养民,“一种阳离子型无孔大环有机化合物及其制备方法和应用”,专利号:ZL202011176930.4;(已转让) 1、曹丽慧,唐小涵,刘欣,徐小倩,王梦,马养民,“一种三维多孔金属锌配位聚合物及其制备方法和应用”,专利号:ZL201910339596.0。(已转让) 四、会议报告: 7、中国化学会第17届固态化学与无机合成学术会议,广西壮族自治区桂林市,邀请报告,2024年10月; 6、中国化学会第四届全国光功能材料青年学者研讨会,陕西省西安市,邀请报告,2024年09月; 5、中国化学会第34届学术年会,第24分会:功能晶态材料,广东省广州市,口头报告,2024年6月; 4、中国化学会第一届电化学能量转换研讨会,海南省海口市,口头报告,2023年12月; 3、《国家科学评论》化学与材料科学前沿论坛,江苏省扬州市,邀请报告,2023年11月; 2、中国化学会第九届全国多酸化学学术研讨会暨第五届全国有机多孔材料学术研讨会,吉林省长春市,邀请报告,2023年5月; 1、中国化学会第九届全国配位化学会议,河南省郑州市,口头报告,2022年08月。 |