承担 的主 要项 目及 成果 | 作为项目负责人，承担项目情况： （1） 国家自然科学基金青年项目：22101164，基于导向策略的过渡金属催化硅甲基Csp3-H键官能化反应研究，结题，主持 （2） 陕西省科技厅基础研究计划项目：2021JQ-530，瞬态导向基/可见光协同促进脂肪醛、酮β-Csp3-H键官能化，结题，主持 （3） 陕西省教育厅专项项目，19JK0148，过渡金属催化羧基导向C-H键磷酰化/脱羧反应研究，结题，主持 （4） 陕西科技大学科研启动基金：2016BJ-67，过渡金属催化惰性碳氢键官能化反应研究，在研，主持 发表论文情况： (1) Xiang Li,* Hang Cheng, Jianghao Shao, Guodong Zhang, Shuilong Zhang Rh(III)-Catalyzed [4 + 1] Annulation of Benzamides with Vinyl Cyclic Carbonates for the Synthesis of Isoindolinones Org. Lett. 2024, 26, 1304–1309. (2) Xiang Li,* Yang Shen, Guodong Zhang, Xin Zheng, Qing Zhao, Zihe Song Ru(II)-Catalyzed Decarbonylative Alkylation and Annulations of Benzaldehydes with Iodonium Ylides under Chelation Assistance Org. Lett. 2022, 24, 5281–5286. (3) Xiang Li,* Qing Zhao, Yang Shen, Ran Ma* Rh(III)-Catalyzed C-H Diamidation and Diamidation/Intramolecular Cyclization of N-Iminopyridinium Ylides with Dioxazolones J. Org. Chem. 2022, 87, 3468-3481. (4) Xiang Li,* Danlu Li, Xiaofei Zhang* Ru(II)-Catalyzed C-H Bond Activation/Annulation of N-iminopyridinium Ylides with Sulfoxonium Ylides Org. Biomol. Chem. 2022, 20, 1475-1479. (5) Xiang Li,* Ruihong Zhang, Yaoting Qi, Tuanli Yao Rhodium(III)-catalyzed C–H activation/annulation of N-iminopyridinium ylides with alkynes and diazo compounds Org. Chem. Front. 2021, 8, 1190-1196. (6) Xiang Li,* Ruihong Zhang, Xiaofei Zhang, Peiyuan Zhu, Tuanli Yao* Silver-Catalyzed Decarboxylative Allylation of Difluoroarylacetic Acids with Allyl Sulfones in Water Chem. Asian J. 2020, 15, 1175-1179. (7) Xiaofei Zhang,* Peiyuan Zhu, Ruihong Zhang, Xiang Li,* Tuanli Yao* Visible-Light-Induced Decarboxylative Cyclization of 2-Alkenylarylisocyanides with α-Oxocarboxylic Acids: Access to 2-Acylindoles J. Org. Chem. 2020, 85, 9503–9513. (8) Xiang Li,* Feng Zhang, Dan Wu, Yirui Liu, Gan Xu, Yanli Peng, Zixiong Liu, Yuxin Huang Rhodium(III)-Catalyzed C-H Alkylation of Heterocycles with Allylic Alcohols in water: A Reusable Catalytic System for the Synthesis of β-aryl ketones. Tetrahedron 2018, 74, 7364-7371. (9) Xiang Li, Siyu Li, Suyan Sun, Fan Yang,* Weiguo Zhu, Yu Zhu, Yusheng Wu*, Yangjie Wu* Direct Decarboxylative Alkynylation of α, α-Difluoroarylacetic Acids under Transition Metal-Free Conditions, Adv. Synth. Catal. 2016, 358, 1699-1704. (10) Xiang Li, Suyan Sun, Fan Yang,* Jianxun Kang, Yusheng Wu*, Yangjie Wu* Palladium-Catalyzed Oxidative Deacetonative Coupling of 4-Aryl-2-methyl-3-butyn-2-ols with H-phosphonates, Org. Biomol. Chem. 2015, 13, 2432-2436. (11) Xiang Li, Fan Yang*, Yangjie Wu*, Yusheng Wu* Copper-Mediated Oxidative Decarboxylative coupling of Arylpropiolic Acids with Dialkyl H-phosphonates in Water, Org. Lett. 2014, 16, 992-995. (12) Xiang Li, Fan Yang*, Yangjie Wu* Palladacycle-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylic Acids with Aryl Chlorides under Air, J. Org. Chem. 2013, 78, 4543-4550. (13) Xiang Li, Fan Yang* and Yangjie Wu* Synthesis of diarylalkynes via tandem Sonogashira/decarboxylative reaction of aryl chlorides with propiolic acid, RSC Adv. 2014, 4, 13738–13741. 发表专利情况： (1) 李翔，张瑞红，张晓斐. 一种可重复利用的催化体系在室温下合成β-芳基酮的方法，中国发明专利，ZL 201911342612.8。 (2) 李翔，朱培元，张晓斐，张瑞红. 一种光催化下2-酰基吲哚化合物的合成方法，中国发明专利，ZL 202010089123.2。 (3) 李翔,张瑞红,张晓斐,朱培元. 一种水相中偕二氟烯丙基化合物的合成方法，中国发明专利，ZL 201911342214.6。 |
